Chemistry of selected elements: properties and reactions

Inorganic Chemistry: Chemistry of Selected Elements

Alkali Metals (Group 1)

⚡️ Alkali metals are the most reactive of all metals. Think of them as the extremely energetic friends who always want to share electrons to become stable.

  • Low density, low melting points.
  • Soft enough to be cut with a knife.
  • Highly reactive with water: Na + H₂O → NaOH + ½ H₂↑
  • Form +1 cations (e.g., Na⁺).

Example reaction with water (Li): 2 Li + 2 H₂O → 2 LiOH + H₂↑

  1. Write the balanced equation.
  2. Identify the oxidation state change.
  3. Predict the gas produced.
Exam Tip: Remember that alkali metals always give up one electron, forming a +1 ion. Use this to balance redox equations quickly.

Alkaline Earth Metals (Group 2)

🧪 These metals are a bit less “hyperactive” than alkali metals but still love to lose two electrons.

  • Higher melting points than alkali metals.
  • Form +2 cations (e.g., Ca²⁺).
  • React with water slowly: Mg + 2 H₂O → Mg(OH)₂ + H₂↑

Reaction with acids: Ca + 2 HCl → CaCl₂ + H₂↑

Exam Tip: For reactions with acids, remember the general formula: M + 2 HX → M(X)₂ + H₂↑. Fill in the blanks quickly.

Transition Metals

🔬 Transition metals are the “versatile artists” of the periodic table, capable of many oxidation states.

  • Often form coloured solutions.
  • Common oxidation states: +2, +3, +4.
  • Example: Fe²⁺ ↔ Fe³⁺ in redox reactions.

Redox example: Fe²⁺ + Cu²⁺ → Fe³⁺ + Cu⁺

  1. Identify the species being oxidised and reduced.
  2. Balance the electrons transferred.
  3. Check charge and mass balance.
Exam Tip: Use the “oxidation number” method to quickly spot which atoms change oxidation state.

Halogens (Group 17)

💡 Halogens are the “stubborn friends” that love to gain one electron to complete their outer shell.

  • High electronegativity.
  • Form -1 anions (e.g., Cl⁻).
  • Reactivity decreases down the group.

Reaction with metals: 2 Cl₂ + 2 Na → 2 NaCl + Cl₂↑

Redox with oxygen: Cl₂ + H₂O → HCl + HClO

Exam Tip: Remember the “halogen rule”: halogens form -1 ions unless they react with metals, where they form salts.

Noble Gases (Group 18)

🌌 Noble gases are the “lonely stars” that rarely react because their outer shells are full.

  • Inert under normal conditions.
  • Used in lighting (Neon) and as inert atmospheres.
  • Can form compounds under extreme conditions (e.g., XeF₂).

Example: Xe + 2 F₂ → XeF₂

Exam Tip: When asked about noble gases, highlight their full valence shell and typical uses rather than reactions.

Summary Table of Selected Elements

Element Symbol Group Typical Oxidation State Common Reaction
Sodium Na 1 +1 Na + 2 H₂O → NaOH + H₂↑
Calcium Ca 2 +2 Ca + 2 HCl → CaCl₂ + H₂↑
Iron Fe Transition +2, +3 Fe²⁺ + Cu²⁺ → Fe³⁺ + Cu⁺
Chlorine Cl 17 -1 Cl₂ + 2 Na → 2 NaCl + Cl₂↑
Xenon Xe 18 0 Xe + 2 F₂ → XeF₂

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